Dr. Alan M. Shiller


Complete resume and additional course information can be found: http://ocean.otr.usm.edu/~w305860

Trace elements in natural waters; marine and estuarine chemistry; chemistry of rivers and weathering; oil spill effects on ocean chemistry; global carbon system; sedimentary fluxes.

At present, most of the work in my lab involves trace element studies, though we are also involved in some oil spill and sediment studies as well as examinations of methane and carbon dioxide. Over the years I have worked in many different areas of geochemistry ranging from sediment studies to radionuclide studies to studies of the oceanic carbon dioxide system. Thus, I am prepared to help students interested in most any sort of geochemically-oriented project.

My lab has a wide variety of research tools including a clean lab, a high resolution inductively coupled plasma mass spectrometer (HR-ICP-MS), methane analyzer, water isotope analyzer, field flow fractionator, ion chromatograph, and flow injection analysis equipment. We're particularly proud of the HR-ICP-MS (Finnigan Element 2) which is far more sensitive than optical ICP and conventional quadrupole ICP-MS instrumentation.

Current Research

Trace elements in rivers and streams, including mechanisms of seasonal concentration variations in the Mississippi River, effect of landscape differences on trace elements in the Yukon River Basin, and the global variability of concentrations.

Trace element and nutrient behavior in the outflow region of the Mississippi River along the Louisiana Shelf. We are also working in Mississippi coastal waters on the east side of the bird-foot delta. New aspects of this work include using Rn and methane as indicators of submarine groundwater discharge and using water isotopes as mixing tracers.

Dissolved trace elements in the ocean. As part of the international GEOTRACES Program (www.geotraces.org), we are participating in various cruises (Atlantic, Pacific, and Arctic Oceans) in which we are constructing sections elements such as gallium (which is a dust input indicator) and barium (a paleo-productivity indicator). The work is funded by the National Science Foundation.

Composition of colloids. Colloids are sub-micron particles and macromolecules and they are an important factor regulating trace element transport and bioavailability/toxicity. In some of our work we utilize small pore size (20 nm) filters to process samples in remote field sites. In other work we use a technique called field flow fractionation that allows colloidal particles to be size fractioned for further analysis.

Chemical effects of the Deepwater Horizon oil spill. We have examined distributions of trace elements, nutrients, polycyclic aromatic hydrocarbons (PAH’s), and methane in submerged plumes in the spill area. The work is funded by the National Science Foundation and the NGI/BP Gulf Research Initiative.



  • Marine Chemistry (MAR 541) Sea water chemistry and cycles and their impact on the marine environment.
  • Estuaries (MAR 655) An introduction to estuary processes and ecology with discussion of the impact of human activities.
  • Aquatic Chemistry (MAR 683) Principles of inorganic and physical chemistry applied to quantitative description of processes in natural waters.
  • Global Carbon System (MAR 641) An examination of the biogeochemical cycling of carbon through global systems with an emphasis on the problem of climate change.
  • Seminar in Marine Science (MAR 689) A course examining the fundamentals of and providing experience in presenting the results of scientific research in scientific meetings.


Selected Publications

(See complete publications list on Google Scholar: http://scholar.google.com/citations?user=A9zbSaUAAAAJ&hl=en)


Roberts, H.M. and A.M. Shiller, 2015. Determination of dissolved methane in natural waters using headspace analysis with cavity ring-down spectroscopy. Analyt. Chim. Acta. 856: 68-73, DOI: 10.1016/j.aca.2014.10.058.

Bera, G., K.M. Yeager, M. Shim, and A.M. Shiller, 2015. Anthropogenic stable cesium in water and sediment of a shallow estuary, St. Louis Bay, Mississippi. Estuarine Coastal and Shelf Science 157: 32-41.  doi:10.1016/j.ecss.2015.02.004.

Crespo-Medina, M., C.D. Meile, K.S. Hunter, A.R. Diercks, V.L. Asper, V.J. Orphan, P.L. Tavormina, L.M. Nigro, J.J. Battles, J.P. Chanton, A.M. Shiller, D.J. Joung, R.M.W. Amon, A. Bracco, J.P. Montoya, T.A. Villareal, A.M. Wood, and S.B. Joye, 2015. Addendum: The rise and fall of methanotrophy following a deepwater oil-well blowout. Nature Geoscience 8: 490. doi:10.1038/ngeo2447.

Rakocinski, C.F., B.H. Comyns, M.S. Peterson, and A.M. Shiller, 2015. Regional patterns in the otolith chemistry of juvenile spotted seatrout (Cynoscion nebulosus) under contrasting hydrological conditions. The Open Fish Science Journal 8: 1-12, DOI: 10.2174/1874401X01508010001.

Joung, DJ and A.M. Shiller, 2014. Dissolved barium behavior in Louisiana Shelf waters affected by the Mississippi/Atchafalaya River mixing zone. Geochimica et Cosmochimica Acta 141: 303-313, doi: 10.1016/j.gca.2014.06.021

Stolpe, B., Z. Zhou, L. Guo, and A.M. Shiller, 2014. Colloidal size distribution of humic- and protein-like fluorescent organic matter in the Northern Gulf of Mexico. Marine Chemistry, doi: 10.1016/j.marchem.2014.05.007.

Joung, DJ. and A.M. Shiller, 2013. Trace element distributions in the water column near the Deepwater Horizon well blowout. Environ. Sci. Technol. 47(5): 2161-2168. doi: 10.1021/es303167p.

Shiller, A.M. and DJ. Joung, 2012. Nutrient depletion as a proxy for microbial growth in Deepwater Horizon subsurface oil/gas plumes. Environmental Research Letters 7: 045301, doi:10.1088/1748-9326/7/4/045301.

Shim, M.-J., P.S. Swarzenski, and A.M. Shiller, 2012. Dissolved and Colloidal Trace Elements in the Mississippi River Delta Outflow after Hurricanes Katrina and Rita. Continental Shelf Research 42: 1-9, doi:10.1016/j.csr.2012.03.007.

Shiller, A.M., 2010 Dissolved Rare Earth Elements in a Seasonally Snow-covered, Alpine/Subalpine Watershed, Loch Vale, Colorado. Geochimica et Cosmochimica Acta 74: 2040-2052.  DOI:10.1016/j.gca.2010.01.019.

Shiller, A.M and G.R. Bairamadgi., 2006. Dissolved Gallium in the Northwest Pacific and the South and Central Atlantic Oceans: Implications for Aeolian Fe Input and a Reconsideration of Profiles. Geochemistry, Geophysics, Geosystems 7, Q08M09, doi:10.1029/2005GC001118.